Definitely Don't Refrigerate...
There are some foods that are actively made worse by refrigeration. These are the items you should absolutely keep away from cold.
Potatoes
Refrigeration causes the starch in potatoes to turn to sugar, and while this might sound like a good thing, it gives them the wrong flavor. The skins will also darken prematurely while cooking, making them look less appetizing.Onions
Here's a weird one. You don't have to refrigerate onions, but you do need to keep them physically separated from the potatoes. Spuds emit moisture and gases that will make your onions rot. Your best bet is to keep onions in the mesh bag they came in—they like air circulation.Garlic
Again, air circulation is key. Garlic bulbs will keep for two months without refrigeration, and if you keep them out of the damp air of the fridge you'll avoid making all your other nearby produce smell like garlic. Some even say that refrigeration will make garlic sprout prematurely.Avocado
Is there anything more delicious and healthy than a ripe avocado? Avocado won't ripen in cold conditions, so unless you need them to keep for awhile, you should let yours live outside the refrigerator until they're ready to eat. There's a popular legend suggesting the presence of the pit prevents browning, so if you only use half of an avocado, be sure to reserve the side with the pit.Tomatoes
Cold breaks down the cell walls in tomato flesh and causes them to become mushy and mealy. For better results, store them at room temperature and keep them out of direct sunlight, which can ripen them early and unevenly.Bananas
Allow bananas to ripen at room temperature, and use your refrigerator when you want to slow the ripening process. Just be aware that refrigeration also happens to turn banana peels brown (though the interior is still unspoiled). Frozen bananas also make a great ice cream replacement for dieters.Melon
Fresh melon—uncut, we should specify—is best stored on the kitchen counter where it can properly ripen and sweeten. Only after you cut up your cantaloupe (or whatever) into bit sized bits should the flesh be refrigerated (but never frozen).
Stone Fruits
Peaches, apricots, nectarines, plums, cherries, and so on should be ripened at room temperature, stem-end down. Only after the fruits start softening slightly to the touch and begin to smell sweet should they be moved to the refrigerator. Shelf life is three to five days after that.Bread
Try to eat your bread before it gets to the point where you need to chill it to stave off mold, because if you end up refrigerating, the loaf will get tough and less tasty. For this reason, a lot of people freeze bread. Freezing preserves the texture, but then you have to deal with defrosting it. And who's got the the time to microwave a slice of bread when they're rushing to catch a train in the morning?Pastries
It's the same story with cookies and pastry. You can store them covered outside the fridge, and it's true they won't last quite as long, but refrigeration causes baked goods to go stale faster. Keep your cannolis on the countertop where they belong.
Hot Sauce
Not all hot sauces are created equal, but if it's a vinegar-based hot sauce like Tabasco, you can almost always safely store it in the pantry for months on end. Cold weakens the flavor and changes the viscosity of the sauce, affecting the pour.Spices
Once again the humid environment of a refrigerator is detrimental to the flavor of spices, and since most can be safely stored for years without refrigeration, there's no benefit to cold storage at all.Honey
It has a practically indefinite shelf life. Don't refrigerate honey. It'll crystallize, and you'll have to squeeze that stupid teddy bear even harder to get it out.Peanut Butter
All-natural peanut butter does have to be refrigerated, because the peanut oil can rise, separate from the mash, and go rancid. Commercially processed peanut butter, on the other hand (like JIF and Skippy), can be stored for months without issue—even if the jar's been opened already. But really, who can't eat a jar of peanut butter in a month? It's delicious, and good for you, too.
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